In this section, you can access to the latest technical information related to the FUTURE project topic.

Synthesis of novel ferrocene-based conjugated microporous polymers with intrinsic magnetism

The combination of conjugated microporous polymers (CMPs) with magnetic property was a meaningful issue in theoretical and practical study. Endowing CMPs with magnetic property can extend its application to the fields like magnetic sensor and magnetic separation. Ferrocene-based conjugated microporous polymers (Fc-CMPs) with intrinsic magnetism were constructed with ferrocene derivative as a building unit by Pd-mediated Sonogashira-Hagihara cross-coupling reaction. Fc-CMPs exhibited excellent porosity, and the BET surface area of Fc-CMPs was up to 520m2/g. The results indicated that the saturation magnetization of Fc-CMPs could be tuned by combining ferrocene derivative with monomers with different ?-conjugated degree.

» Author: Gen Li, Qingquan Liu, Bo Liao, Lijuan Chen, Hu Zhou, Zhihua Zhou, Bijiang Xia, Jing Huang, Bin Liu

» Reference: European Polymer Journal, Volume 93

» Publication Date: 01/08/2017

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