In this section, you can access to the latest technical information related to the FUTURE project topic.

An uncommon 3D Co5-cluster-based metal-organic framework: Synthesis, structure and magnetism

A highly connected metal–organic framework (MOF), namely, [Co5(?3-OH)2(iapt)4(4,4?-bipy)0.5(H2O)·CH3CN·3H2O] (1) (H2iapt=5-aminoisophthalic acid and 4,4?-bipy=4,4?-bipyridine), is reported. 1 shows a complicated pentanodal 4,4,4,4,13-c 3D net with (43)(43)(43)(43)(420·514·623·78·813) topology based on an uncommon Co5 cluster. The magnetic analysis reveals antiferromagnetic interactions in 1, and both the local spin–orbit coupling of octahedral Co(II) ions and the antiferromagnetic interactions are the primary factors in the magnetic behaviour.

» Author: Yu Wu, Bao-Hong Li, Jian-Qiang Liu, Bin Xie, Hiroshi Sakiyama, Stuart R. Batten

» Reference: Inorganic Chemistry Communications

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