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Experimental investigation and thermodynamic calculation of the Fe–Si–Sn system

Phase equilibrium of the Fe–Si–Sn ternary system was investigated using equilibrated alloys. The samples were characterized by means of scanning electron microscopy equipped with energy dispersive X–ray spectrometry and X–ray diffraction. Isothermal sections of the Fe–Si–Sn system at 700°C and 890°C each consists of 5 three–phase regions. No ternary compound was found at those two temperatures. The solubility of Sn in the Fe–Si binary phases and the solubility of Si in the Fe–Sn binary phases is limited. Furthermore, thermodynamic extrapolation of the Fe–Si–Sn system was carried out. Calculated solidification path and phase relationship agreed well with experimental results.

» Author: Xinming Wang, Bin Zhou, Zhiqiu Guo, Ya Liu, Jianhua Wang, Xuping Su

» Reference: Calphad, Volume 57

» Publication Date: 01/06/2017

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