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In this section, you can access to the latest technical information related to the FUTURE project topic.
Staged pyrolysis of biomass to probe the evolution of fractions of bio-oil
Bio-oil is a complex mixture of organics and each group of chemicals has a varied response to pyrolysis temperatures. This was investigated via the staged pyrolysis of poplar sawdust, cellulose, and lignin by consecutively increasing temperature to 250, 350, 450, and 550??C, respectively. The results showed that 350??C was the boundary temperature for formation of majority of organics from sawdust and cellulose and more than half of organics from lignin. The further increase of temperature to 550??C mainly promoted the aromatization of reaction intermediates from aliphatic components. The staged pyrolysis also facilitated the charring reactions, generating the bio-oil with more light organics including anhydrate sugars, ketones, aldehydes, and phenolics. The enhanced charring reactions promoted the carbonization reactions via deoxygenation, making biochar carbon-rich and thermally more stable. Additionally, the staged pyrolysis also impacted the morphologies and evolution of the functionalities of biochar via influencing the volatile-char interactions.
» Author: Chao Li, Yuannian Li, Yuchen Jiang, Lijun Zhang, Shu Zhang, Kuan Ding, Bin Li, Shuang Wang, Xun Hu
» Reference: Energy, Volume 263, Part D
» Publication Date: 15/01/2023
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