In this section, you can access to the latest technical information related to the FUTURE project topic.

Improvement of rheology and mechanical properties of PLA/PBS blends by in-situ UV-induced reactive extrusion

Blending with biodegradable poly (butylene succinate) (PBS) is an effective way for improving the performance of PLA. However, the property of the blends is not significantly improved due to poor compatibility between the two polymers. Herein, we propose a simple method to prepare biodegradable PLA/PBS blends successfully by UV-induced reactive extrusion. Multifunctional monomer trimethylolpropane tri-acrylate (TMPTA) is used as chain extender to react with PLA and PBS to generate graft copolymers at the PLA/PBS interface. Addition of glycidyl methacrylate (GMA) could further promote the graft reaction, thus increase the compatibility and the mechanical properties of the blends. The occurrence of the long chain branched reaction between the PLA and PBS is evidenced by the rheological results and Fourier-transform infrared spectroscopy analysis. Appropriate amount of GMA reduces the size of dispersed PBS phase and enhances the interfacial strength. The crystallization of PLA is effectively improved, as evidenced by the increased cool crystallization peak and apparent enhancement crystallinity. Ultimately, PLA/PBS blends compatibilized with GMA/TMPTA exhibit a remarkable improvement in elongation at break of 341%, notched impact strength and a preferable maintenance of 50?MPa in tensile strength.

» Author: Fu-Lu Chang, Bin Hu, Wei-Tao Huang, Lun Chen, Xiao-Chun Yin, Xian-Wu Cao, Guang-Jian He

» Publication Date: 27/10/2022

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