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A 3D Ni(II)-MOF with frl topology based on 2-(1-imidazole)-1-hydroxyl-1,1?-ethylidenediphosphonic acid and N,N?-donor co-ligand: Synthesis, structure and magnetic property

Publication date: August 2015
Source:Inorganic Chemistry Communications, Volume 58

Author(s): Xue-Qian Wu , Min-Le Han , Guo-Wang Xu , Bin Liu , Dong-Sheng Li , Jian Zhang

A new 3D Ni(II)-MOF {[Ni3(ImhedpH)2(4,4?-bipy)]·4,4?-bipy·4H2O} n (1), based on 2-(1-imidazole)-1-hydroxyl-1,1?-ethylidenediphosphonate and 4,4?-bipyridyl, is presented, which possesses a (4,4)-connected frl-(42·64)4(64·82) network and shows ferrimagnetism and field-induced magnetic transition from ferrimagnetism to fully polarized state.
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