In this section, you can access to the latest technical information related to the FUTURE project topic.

Synthesis, Electronic Properties and Reactivity of [B12X11(NO2)]2? (X=F?I) Dianions

The new closo?dodecaborates [B12X11(NO2)]2? (X=halogen) were synthesized in high yields and fully characterized by structural and spectroscopic methods. The artwork illustrates its remarkable electronic and chemical stability. However, thermally it easily cleaves off an NO radical. The resulting double negatively charged radical [B12X11O]2?. is highly reactive and can recombine with NO in the gas phase to the even more stable unprecedented [B12X11(ONO)]2? anions. More information can be found in the Full Paper by C. Jenne, J. Warneke, et?al. (DOI: 10.1002/chem.202003537).

» Author: Knut R. Asmis, Bj?rn B. Beele, Carsten Jenne, Sebastian Kawa, Harald Knorke, Marc C. Nierstenh?fer, Xue?Bin Wang, Jonas Warneke, Ziyan Warneke, Qinqin Yuan

» Reference: doi:10.1002/chem.202004113

» Publication Date: 02/10/2020

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