Wheat stalk as an agricultural waste was used for the extraction of microcrystalline and nanocrystalline cellulose via thermochemical and mechanical treatments, compounded with poly(butylene adipate?co?terephthalate) as a biodegradable polymer. Compared to the neat polymer, the composites showed enhanced surface hydrophilicity and higher water absorption thereby increasing the ability of degradation under soil composting for few months.An agricultural waste, the wheat stalk, was used for the extraction of microcrystalline cellulose (MCC) and nanocrystalline cellulose (NCC) via a series of thermochemical and mechanical treatments. The MCC and NCC were then compounded with the biodegradable polymer, poly(butylene adipate?co?terephthalate), PBAT, by melt mixing. The properties of the composites were evaluated by soil composting, contact angle and water absorption measurements, scanning electron microscopy (SEM) and gel permeation chromatography (GPC). The cellulosic filler was found, as per SEM results, to uniformly disperse in the polymer matrix forming a quite homogeneous composite which visibly degraded completely within a few months under soil composting and showed high water absorption, these properties being enhanced with the filler content. Compared to the neat PBAT, the composites showed enhanced surface hydrophilicity thereby increasing the ability of degradation. In spite of seemingly remarkable change in mechanical stability of the polymers under soil burial for several months, relatively low lowering of the molecular weight was observed. ? 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48149.

» Author: Jyoti Giri, Ralf Lach, Wolfgang Grellmann, Md. Abu Bin Hasan Susan, Jean?Marc Saiter, Sven Henning, Vimal Katiyar, Rameshwar Adhikari

» Reference: doi:10.1002/app.48149

» Publication Date: 06/08/2019

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