In this section, you can access to the latest technical information related to the FUTURE project topic.

Synthesis and Structures of Stable PtII and PtIV Alkylidenes: Evidence for ??Bonding and Relativistic Stabilization

It's all relative: A homologous series of Group?10 PCcarbeneP complexes were prepared and the bonding in the M=C moiety probed by experimental and computational techniques to show that relativistic stabilization is significant in the platinum carbene.Isolable cationic PtII and PtIV alkylidenes, proposed intermediates in catalytic organic transformations, are reported. The bonding in these species was probed by experimental, structural, spectroscopic, electrochemical and computational methods, providing direct evidence for ??bonding, the often?theorized relativistic stabilization of these species, and the influence of oxidation state.

» Author: Etienne A. Lapierre, Warren E. Piers, Jian?Bin Lin, Chris Gendy

» Reference: doi:10.1002/chem.201806065

» Publication Date: 05/03/2019

» More Information

« Go to Technological Watch



AIMPLAS Instituto Tecnológico del Plástico

C/ Gustave Eiffel, 4
(València Parc Tecnològic) - 46980
PATERNA (Valencia) - SPAIN

PHONE

(+34) 96 136 60 40

EMAIL

Project Management department - Sustainability and Industrial Recovery
life-future-project@aimplas.es